The vitamin C in its pure form, also known asL-ascorbic acid (INCI name: Ascorbic Acid), appears as yellowish crystals or powder. This type of ascorbic acid is the most well-known of all and allows for excellent results in terms of overall skin and complexion improvement. However, its acidic pH around 3.5 must be maintained to avoid oxidation problems. Indeed, unstable vitamin C can have effects contrary to those originally sought and promote the formation of free radicals, causing oxidative damage to skin cells and accelerating their overall ageing.
However, reducing the pH of a cosmetic formula can lead to skin sensitisation, as the natural pH of the skin is around 5.5 - 6. To incorporate vitamin C into a cosmetic formula that respects the skin's pH, certain derivatives exist. Even though their effectiveness cannot be compared to that of pure L-ascorbic acid, they still provide relevant benefits to the skin, particularly for brightening dull complexions and combating signs of ageing.
Generally, these derivatives are combinations of ascorbate (vitamin C in a non-acidic form) with alkalising minerals (calcium, magnesium, sodium, etc...). Here are examples of vitamin C derivatives frequently used in the formulation of skincare products:
The sodium ascorbyl phosphate (INCI name: "Sodium Ascorbyl Phosphate"):
This refers to a water-soluble form of pure Vitamin C, which is much more stable against oxidation. It is particularly interesting and widespread in skincare because it has the ability to transform into ascorbic acid once applied to the skin. This form of Vitamin C also has the advantage of being less irritating, making it more suitable for sensitive and atopic skin.
The Magnesium Ascorbyl Phosphate (INCI name: "Magnesium Ascorbyl Phosphate"):
This is one of the most stable forms of vitamin C. However, a study conducted by the Duke University Medical Center found that this substitute did not increase the natural levels of vitamin C in the skin.
Thetetraisopalmitateofascorbyl (INCI name: "Ascorbyl Tetra Isopalmitate"):
This is a oil derived from pure L-ascorbic acid ; it easily penetrates the skin and can be used topically at high concentrations without risk.
Furthermore, there are other derivatives of vitamin C in skincare, whose I.N.C.I. names are "Ascorbyl Palmitate", "Tetrahexyldecyl Ascorbate", "Ascorbyl Glucoside" and "3-O Ethyl Ascorbate".