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Informations sur le pH de la peau.

Everything you need to know about the pH of the skin.

In the world of the cosmetics industry, the term pH is increasingly being used. This is justified as maintaining the skin's pH is essential for healthy skin. But what is pH? Why is the skin's pH important? Elements of the answer in this article.

Summary
Published May 24, 2022, updated on June 20, 2024, by Sandrine, Scientific Editor — 6 min read

What is pH?

The potential Hydrogen (pH) of an aqueous solution measures its acidic or alkaline character. More specifically, it measures the concentration of hydronium ions (H3O+) in an aqueous solution. The chemical formula that links them is as follows pH = -log [H3O+].

The pH values range between 0 and 14 :

  • If the pH is between 0 and 7 , the solution is acidic .

  • If the pH is equal to 7 , the solution is neutral ;

  • If the pH is between 7 and 14 : the solution is basic (alkaline).

Thus, the lower the pH value, the more acidic the solution, and the higher the pH value, the more alkaline the solution.

There are two main methods for measuring the pH of a solution. The first involves using pH paper , which changes colour depending on the pH of the aqueous solution it is immersed in. The second, more accurate method, relies on the use of pH electrodes connected to a pH meter.

As mentioned earlier, the pH scale is a logarithmic scale and not a linear one. Therefore, a pH of 3 is 10 times more acidic than a pH of 4 and 100 times more acidic than a pH of 5.

The pH of the skin.

The skin is the largest organ of our body. It serves as our body's first line of defence against external aggressions.This protective role is made possible thanks to the acidic pH around 5.5 of the skin's hydrolipidic film. The hydrolipidic film, located on the skin's surface, is a complex emulsion primarily composed of sweat and sebum. The acidic pH of the hydrolipidic film is a key factor in the homeostasis of the barrier, the integrity of the stratum corneum, and antimicrobial defence : we refer to this as "acid mantle" or "acidic barrier". Indeed, ceramides, which are essential constituents of the stratum corneum, are synthesised at an acidic pH by pH-dependent enzymes.

The pH of the skin varies depending on endogenous factors, but also exogenous ones. Among the endogenous factors that can alter the pH, we can mention:

  • Age : The skin pH of newborns is significantly higher than that of adults, with a value close to 7 (neutral pH), and this value decreases over time;

  • Skin Zones : The pH of the skin is higher in certain areas of the body (armpits, groin, intra-mammary area...). In the armpits, a higher pH leads to colonisation by certain resident bacteria that produce odours, such as propionic bacteria and staphylococci. Thus, deodorants containing citrates reduce the pH and inhibit bacterial activity;

  • Skin Type : Indeed, teenagers with oily and acne-prone skin tend to have a more alkaline skin pH.

Other endogenous factors, such as gender or skin pigmentation, can also affect pH levels. Indeed, due to a higher production of sebum and sweat than women, men have a more acidic skin pH. Furthermore, it has been proven that individuals with darker skin have a more acidic skin pH due to a higher presence of epidermal lipids. Besides endogenous factors, there are exogenous factors that can alter pH levels. Among them, we primarily find:

  • Some cosmetic products : This is the case with soaps for instance. Indeed, these have a basic pH around 9 - 10 which disrupts the natural acidic pH of the hydrolipidic film, thus causing skin dryness and a risk of infections.

Please note : Unlike soaps which, with a basic pH, disrupt the skin's pH, cosmetics with an acidic pH between 3 and 4, such as products containing vitamin C or fruit acids, are beneficial for the skin because the enzymes responsible for the production of ceramides (lipid constituents of the skin barrier) have an optimal acidic pH. Thus, they help to strengthen the skin barrier. Beware! Some products like lemon juice, whose properties are praised on the internet, have a too acidic pH (2.4) and are therefore irritating to the skin.

Deregulating the skin's pH leads to unfortunate consequences for the skin. Therefore, it is important touse cosmetic products with a pH between 3 and 7.

Source:

  • YOSIPOVITCH G. & al. Skin pH: From Basic Science to Basic Skin Care. ActaDermato-Venereologica (2013).

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